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Home » Products » Chemical Series » Polyether series » Allyl Polyethylene Glycol APEG Series » Allyl Polyethylene Glycol APEG-400 (CAS 27274-31-3) - Water-Soluble Non-Ionic Surfactant for Concrete Superplasticizer

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Allyl Polyethylene Glycol APEG-400 (CAS 27274-31-3) - Water-Soluble Non-Ionic Surfactant for Concrete Superplasticizer

Allyl Polyethylene Glycol APEG-400 (CAS 27274-31-3) is a non-ionic, allyl-functionalized polymer (appearance: pale yellow liquid at 25°C). With a hydroxyl value of 127~155 mgKOH/g, pH 5.0–7.0 (1% aqueous solution), and water insolubility ≥2.10 mmol/g, it serves as a versatile industrial raw material, valued for its reactivity and compatibility.
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Allyl Polyethylene Glycol APEG-400 (CAS 27274-31-3) Overview

Allyl Polyethylene Glycol APEG-400 (CAS 27274-31-3) is a high-purity, non-ionic polymer with allyl functional groups. As a water-soluble, low-viscosity ethylene oxide adduct, it exhibits excellent reactivity and compatibility. Primarily used as a key monomer for polycarboxylate superplasticizers in construction, it enhances concrete workability and strength. Additionally, its hydrophilic and thermally stable properties make it ideal for emulsifiers, polymerization co-monomers, and additives in textiles, coatings, and detergents. Industrial-grade APEG-400 ensures consistent performance, meeting strict quality standards for diverse manufacturing and construction applications.


Product Advantage

  1. High Reactivity & Functional Versatility

    APEG-400 features allyl groups that enable efficient copolymerization with unsaturated monomers (e.g., acrylic acid). Its hydroxyl value (101–125 mgKOH/g) ensures stable bonding, making it a reliable building block for modified polymers and high-performance additives.

  2. Excellent Compatibility & Solubility

    As a water-soluble (and multi-solvent-soluble) non-ionic polymer, it mixes seamlessly with most construction, textile, and coating formulations. Its pale yellow liquid form (25°C) allows easy handling and uniform blending in production.

  3. Strict Quality Consistency

    Our APEG-400 meets standardized technical benchmarks (pH 5.0–7.0, water insolubility ≥2.10 mmol/g), with batch-to-batch stability verified by industrial-grade testing—ideal for large-scale manufacturing.

  4. Multi-Scenario Adaptability

    Beyond construction, its thermal stability and reactivity suit applications in emulsifiers, textile auxiliaries, and polymer modifiers, delivering consistent performance across diverse industrial processes.



Technical Specifications 

Parameter
Specification for APEG-400
Chemical Name
Allyl polyoxyethylene ether (Allyl polyethylene glycol)
CAS Number
27274-31-3
Type
Non-ionic polymer
Appearance (25°C)
Pale yellow liquid
Hydroxyl Value
127~155 mgKOH/g (determined by acetylation method)
pH Value (1% Aqueous Solution)
5.0–7.0 (measured by pH meter at 25°C)
Water Insolubles
≥2.10 mmol/g (determined by solvent extraction method)
Molecular Weight
Approx. 400 g/mol (calculated from hydroxyl value)
Moisture Content
≤0.5% (Karl Fischer titration)
Viscosity (25°C)
50–80 mPa·s (Brookfield viscometer, spindle 2, 60 rpm)
Purity
≥99.0% (gas chromatography)
Flash Point
≥180°C (closed-cup method)
Storage Stability
Stable for 12 months (dry, ventilated conditions, 5–30°C)


Product Uses

  1. Polycarboxylate Superplasticizer Raw Material

    It is a core monomer for polycarboxylate superplasticizers in construction. When polymerized, it enhances concrete's workability, reduces water usage, and boosts strength (suitable for C600+ high-performance concrete in large projects like bridges).

  2. Polymer Modifier & Co-monomer

    Its allyl groups enable copolymerization with unsaturated compounds, used to modify adhesives, coatings, and high-molecular materials—improving product bonding and durability.

  3. Industrial Additive

    Serves as an emulsifier in detergents, a solubilizer in textile auxiliaries, and a compatibility agent in coating formulations, enhancing product functionality and stability.


Product Operate Guide

For superplasticizer production: Mix APEG-400 with acrylic acid (molar ratio adjusted per formula) in a reactor; heat to 70–80°C, add initiators (e.g., ammonium persulfate), and react for 3–4 hours. Stir uniformly during blending to ensure full polymerization. Store the finished product in sealed containers at room temperature.


FAQ

  1. What is the shelf life of APEG-400?

    It has a 12-month shelf life when stored in a dry, ventilated area (avoid direct sunlight). Sealed packaging prevents moisture contamination, which could affect its hydroxyl value.

  2. Is APEG-400 suitable for high-temperature processes?

    Yes, it maintains thermal stability in typical industrial reaction temperatures (≤100°C), so it can be safely used in polymerization or blending processes under standard operating conditions.

  3. Can APEG-400 be mixed with other surfactants?

    As a non-ionic polymer, it is compatible with most anionic/cationic surfactants. Test small batches first to confirm blending effects before large-scale use.


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